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Traditionally for me 7-10 and 2-5 have usually been the best times for me. Also depends on the time of year and what I am fishing for.
I have caught my big pikes (big as in 10lbers plus) randomly throughout the day with no real pattern. I seem to feel as if there is a flurry of activity on Lake Champlain around 10-11 in the am though? Maybe im nuts... I always have the best luck in the mornings all around from a numbers game...
The late morning bite on Champlain has always puzzled me
I second that, Dad always calls it the "morning run" and then the "afternoon run"
Fish all day you won't miss the fun!