Not a biologist or an expert. But walleye do need a combination of factors to spawn and reporduce successfully. Many waters are simply not suitable for repro and will never have it. Obviously gravel bottoms are the first key. But temp, O2, and water PH during spawn and hatch time are all important.
Becuase its an unatural impoundment has nothing to do with repro. Many eyes thrive in man-made impoundments. Heck, there are waters that stocked eyes can live and live well. But will not have any reproduction.
My home state has stocked hundreds of our waters with walleyes over the past 100+ years. Natural reproduction has only been found in three!! And only one has enough repro to offer a consistant fishery. We simply do not have the water chemisty to have repro. Now PA is allot different, and obviously has more walleye than we will ever have. But that dosn't mean any water with male and female eyes will have signifigant repro.
If you google "walleye reproduction" I am sure you can find some info on what factors are required for sucessful walleye spawn.